Properties of Electrons
The dualism wave/particle is quantitatively described by the De Broglie equation:
$$\lambda = \frac{h}{p}$$
with \(\lambda\): wavelength, \(h\): Planck constant, \(p\): momentum.
The energy of accelerated electrons is equal to their kinetic energy:
$$E = eU = \frac{m_0v^2}{2}$$
with \(U\): acceleration voltage, \(e\): charge, \(m_0\): rest mass and \(v\): velocity of the electron.
These equations can be combined to calculate the wave length of an electron with a certain energy:
$$p = m_0v = \sqrt{2m_0eU}$$
$$\lambda = \frac{h}{\sqrt{2m_0eU}} \simeq \frac{1.22}{\sqrt{U}} \rm{nm}$$
At the acceleration voltages used in TEM, relativistic effects have to be taken into account (s. Table):
$$\lambda = \frac{h}{\sqrt{2m_0eU(1 + \frac{eU}{2m_0c^2})}}$$
Rest mass of an electron: \(m_0\) = 9.109∙10-31 kg
Speed of light in vacuum: \(c\) = 2.998∙108 m/s